Monday, January 30, 2006

OXIDATION & REDUCTION

There are basically 4 definitions of oxidation and reduction:

OXIDATION

1) Increase in oxidation states

Eg: Fe 2+ ---> Fe 3+

An increase of oxidation staes from 2+ to 3+ ( obvious, isn't it? )

2) Gain of oxygen atoms

Eg: Pb + CuO --> PbO + Cu

In this case, Lead (Pb) has gain 1 oxygen atom to form lead(II) oxide (PbO)

3) Lost of hydrogen atoms

Eg: 2 H2S (g) + SO2(g) ---> 2H2O(l) + 3S (s)

In this case, hydrogen sulphide (H2S) has lost 2 hydrogen atoms to form sulphur (S)

Note: do not be CONFUSED by the ratio: 2H2S.
We are interested in the formula, H2S instead!

4) Loss of electrons

Actually, if you look closely, the LOST of electrons is similar to the oxidation states!!!

Why Do I Say That?

Consider this example,
Fe 2+ ---> Fe 3+2+ means lost of 2 electrons and 3+ means lost of 3 electrons.In this case, we say that Fe 2+ is oxidised to Fe 3+.
Compare the oxidation states, isn't 2+ a gain of OXIDATION STATES to 3+ ??

Similarly,

REDUCTION

1) Decrease in oxidation states

Eg: Zn 2+ ---> Zn

From oxidation states of 2+ to 0 ( a decrease in oxidation states )

2) Loss of oxygen atoms

Eg: Pb + CuO ---> PbO + Cu

Copper (II) oxide has lost 1 oxygen atom to form Cu

3) Gain in hydrogen atoms

Eg: N2 + 3H2 ---> 2 NH3

Nitrogen (N2) has gain 2 hydrogen atoms to form ammonia (NH3)

4) Gain of electrons

Eg: Zn 2+ + 2 e- ---> Zn

Zinc ion has accepted 2 electrons to become Zinc ztom
or
Zinc ion has decrease in its oxidation state from 2+ to zero.

( the first rule about decrease in oxidation states )