Monday, January 30, 2006

CHEMICAL BONDS

Ionic Compounds

Ionic compounds are formed by metal (gp 1-3) and non-metal (gp 4-7)

Properties
-High melting point and boiling point ( considered as one point in exam ).

-Soluble in water.

-Conduct electricity in molten (hot liquid ) and in aqueous states
Note: does not conduct electricity in solid states!!!

Metal conduct electricity in molten and in solid states.

Covalent Compounds

Covalent compounds are formed only by non-metal elements.

Properties
-Low melting and boiling points

-Soluble in organic solvents

-Poor conductor of electricity

EXCEPTION: HCl is a good conductor of electricity.
Reason: When HCl dissolves in water, it dissociates to produce H+ and Cl-. It is the free mobile ions that conduct electricity! (Typical MCQ Question! )

(Typical Structure Question)

Question: Both sodium chloride and chlorine gas are compounds of chlorine; sodium chloride exist as a solid while chlorine exist as a gas. Explain why.

Answer:
Sodium chloride is an ionic compound [ 1mark ]. A large amount of energy is needed to overcome the strong electrostatic forces of attraction between oppositely charged ions [ 1mark] . Hence high melting point. This is why it exist as a solid at room
temperature.

Chlorine gas is a covalent substance [ 1mark]. A small amount of energy is needed to overcome the weak intermolecular force of attraction between the molecules [ 1mark]. Hence low melting point. This is why it exist as a gas at room temperature.

Note: Although 'Hence high melting point. This is why it exist as a solid at room temperature.' has no mark allocation, this phrase has to be included for the completeness of answer!