Monday, January 30, 2006

ALKENES

Formula of alkene :

CnH2n

Nomenclature

all alkanes begin with the prefix as mentioned below and ending with -ene

there is no methene ( 1 carbon )

(2 carbon atoms ) eth-

( 3 carbon atoms ) prop-

( 4 carbon atoms ) but-

( 5 carbon atoms ) pent-

( 6 carbon atoms ) hex-

( 7 carbon atoms ) hept-

( 8 carbon atoms ) oct-

( 9 carbon atoms ) non-

(10 carbon atoms ) dec-

Properties of alkene

1) Combustion

Burns in plentify supply of air, it produces carbon dioxide and water.

If INCOMPLETE COMBUSTION, it gives soot, carbon monoxide, carbon dioxide and water.

2) Hydrogenation

C2H4 + H2 ---> C2H6 (ethane)

3) Bromination

C2H4 + Br2 ---> C2H4Br2

** This is bromine test: used to distinguish between alkane and alkene ** ( Typical Structure Question!)

Alkene: Aqueous bromine will decolourised.
Alkane: Aqueous bromine remains unchanged.

4) Hydration

C2H4 + H2O ---> C2H5OH (ethanol)

Another method to prepare ethanol is 'fermentation'

C6H12O6 ---> 2 C2H5OH + 2 CO2

Conditions: yeast and temperature: 25'C.

5) Cracking

To break less useful linger chains into smaller useful fractions.

Conditions: 400°C - 700°C , silicon dioxide /aluminum oxide as catalyst.