Sunday, February 1, 2009

ELECTROLYSIS

Molten

Ions attracted to the cathode: Only positive ions ( metal ions )

Ions attracted to the anode: Only negative ions ( non- metal ions )

Cathode: Metal
Anode: Non-metal

Aqueous

Ions attracted to the cathode: Only positive ions
( non-reactive metal ions and hydrogen ions )

Ions attracted to the anode: Only negative ions
( non-reactive metal ions and hydroxide ions
Cathode: Non-reactive metal or Hydrogen gas
Anode: Halogen ( for concentrated )or oxygen ( for dilute cases )

Aqueous ( concentrated / dilute )

Concentrated :
Cathode: non-reactive metal or hydrogen gas
Anode: halogen or oxygen gas.

Dilute
Cathode: non-reactive metal or hydrogen gas
Anode: oxygen gas

If the electrode is reactive, it often dissolves in electrolyte.

Electric Cell ( Simple Cell)

• The further apart the metals are in the reactivity series, the greater the voltage.
• The more reactive metal is placed at cathode. Eg: Zinc at cathode; Copper at anode.
• Any salt solution can be used at electrolyte.